| 大环二芳基庚烷类化合物的波谱特征 |
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| 引用本文： | 张毅,刘祎,孟大利,李铣.大环二芳基庚烷类化合物的波谱特征[J].波谱学杂志,2010,27(4):669-677. |
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| 作者姓名： | 张毅 刘祎 孟大利 李铣 |
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| 作者单位： | 1. 重庆市药品检验所，重庆 401121；
2. 沈阳药科大学 基于靶点的药物设计与研究教育部重点实验室，辽宁 沈阳 110016 |
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| 摘 要： | 通过查阅国内外相关文献和书籍，对大环联苯型二芳基庚烷和大环二苯醚型二芳基庚烷类化合物的结构特征，紫外，红外，核磁共振波谱和改良Mosher法测定绝对构型进行综述. 现已研究的来源于天然产物的大环二芳基庚烷类化合物结构上各具特征，尤以大环二苯醚型二芳基庚烷类化合物6位H最有代表性. 大环二芳基庚烷类化合物波谱特征的研究为人们鉴定结构提供了重要的依据.
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| 关 键 词： | 核磁共振(NMR) 波谱特征 大环二芳基庚烷 综述 Mosher法 |
| 收稿时间： | 2010-01-20 |
Spectral Characteristics of Cyclic Diarylheptanoids |
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| ZHANG Yi,LIU Yi,MENG Da-li,LI Xian.Spectral Characteristics of Cyclic Diarylheptanoids[J].Chinese Journal of Magnetic Resonance,2010,27(4):669-677. |
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| Authors: | ZHANG Yi LIU Yi MENG Da-li LI Xian |
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| Institution: | 1. Chongqing Institute for Drug Control, Chongqing 401121, China;;
2. Key Laboratory of Structure Based Drug Design & Discovery, Ministry of Education, Shenyang Pharmaceutical University, Shenyang 110016, China |
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| Abstract: | Structural and spectral characteristics of the cyclic diarylheptanoids were reviewed. The UV, IR and NMR characteristics of cyclic diarylheptanoids were summarized, as well as the methods used to determine the absolute configuration of these compounds. It was shown that natural cyclic diarylheptanoids have different structural characteristics, particularly the H-6 of cyclic diphenyl ether diarylheptanoids. This work will provide a basic reference for studying the structure of the cyclic diarylheptanoids. |
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| Keywords: | NMR spectral characteristics cyclic diarylheptanoids review mosher method |
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