| Cyanide-bridged WVMnIII single-chain magnet based on an octacoordinate [W(CN)6(phen)]? anion |
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| 作者姓名： | LEE JinWuk LIM KwangSoo YOON JungHee RYU DaeWon KOO BongHo KOH EuiKwan HONG ChangSeop |
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| 作者单位： | Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-713, Korea;Nano-Bio System Research Team, Korea Basic Science Institute, Seoul 136-713, Korea |
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| 基金项目： | supported by the National Research Foundation of Korea Funded by the Korean Government (2011-0003264);by the Priority Research Centers Program through the National Research Foundation of Korea (NRF) Funded by the Ministry of Education, Science and Technology (NRF20110018396) |
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| 摘 要： | Reaction of unique [W(CN)6(phen)]- with a magnetically anisotropic Mn Schiff base yielded a WⅤ(5d)-MnⅢ(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.
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| 关 键 词： | tungsten manganese cyanide crystal structure single-chain magnet |
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