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Characterization of vibrational resonances of water-vapor interfaces by phase-sensitive sum-frequency spectroscopy
Authors:Ji N  Ostroverkhov V  Tian C S  Shen Y R
Institution:Department of Physics, University of California, Berkeley, CA 94720, USA.
Abstract:Phase-sensitive sum-frequency spectroscopy provides correct characterization of vibrational resonances of water-vapor interfaces and allows better identification of interfacial water species contributing to different parts of the spectra. Iodine ions emerging at an interface create a surface field that tends to reorient the more loosely bonded water molecules below the topmost layer.
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