Solvent effects on oxygen atom transfer reaction between manganese(V)-oxo corrole and alkene |
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| Authors: | Lan Yua Qi Wanga Lu Daia Wei-Ying Lia Rong Chena Mian HR Mahmooda Hai-Yang Liua Chi-Kwong Changb a |
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| Institution: | Department of Chemistry,South China University of Technology,Guangzhou 510640,China b Department of Chemistry,Michigan State University,E.Lansing,MI 48824,USA |
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| Abstract: | Pseudo-first order reaction rate constants of 5,10,15-tris(pentafluorophenyl)corrole Mn(V)-oxo (F15CMn(V)-oxo), 5,15-bis(pentafluorophenyl)-10-(phenyl)corrole Mn(V)-oxo (F10CMn(V)-oxo), 5,15-bis(phenyl)-10-(pentafluorophenyl)corrole Mn(V)-oxo (F5CMn(V)-oxo) and 5,10,15-tris(phenyl)corrole Mn(V)-oxo (F0CMn(V)-oxo) with a series of alkene substrates in different solvents were determined by UV–vis spectroscopy. The results indicated that the oxygen atom transfer pathway between Mn(V)-oxo corrole and alkene is solvent-dependent. |
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| Keywords: | Corrole Mn(V)-oxo corrole Oxygen atom transfer reaction Solvent effect |
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