An entrant of smaller fullerene: C56 captured by chlorines and aligned in linear chains |
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| Authors: | Tan Yuan-Zhi Han Xiao Wu Xin Meng Ye-Yong Zhu Feng Qian Zhuo-Zhen Liao Zhao-Jiang Chen Ming-Hui Lu Xin Xie Su-Yuan Huang Rong-Bin Zheng Lan-Sun |
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| Affiliation: | State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China. |
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| Abstract: | A smaller fullerene C56 (#913) is stabilized, isolated, and crystallographically characterized as C56Cl10. The geometric parameters of C56Cl10 imply the otherwise unstable cage of C56 can be stabilized by chlorination through releasing its surface strains and maintaining fragmental aromaticity. An unexpected C Cl...ClC short contact, as well as the linear alignment with pearl-necklace-shaped, is revealed in C56Cl10 crystal. |
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