丙烯聚合新催化剂的结构特征

用X射线衍射法测定了索尔维型丙烯聚合新催化剂的微晶粒大小为100A左右,比其它方法所制得的同类型催化剂微晶粒要小;并发现催化剂活性与微晶粒大小几乎成线性关系,微晶粒越小催化活性越高。 用ST-03型比表面、孔径分布测定仪研究了催化剂的孔结构。结果表明本催化剂具有较大的比表面和孔体积及粗细孔均备的优良孔结构,保证钛活性中心的充分利用,因而催化剂表现出较高的催化活性。

THE STRUCTURAL CHARACTERISTICS OF A NEW PROPYLENE POLYMERIZATION CATALYST

The crystallite dimensions of a new solvay type catalyst for propylene polymerization were determined from the data of breadth of X-ray diffraction lines at half peak intensity. The crystallites have the size of about 100 A and they are smaller then those prepared by other methods. Their catalytic activity increases linearly with decreasing crystallite size.Surface area and pore structure of the catalyst were determined by elution chro-matographic method on model ST-03 analyzer. Our results showed that such catalyst possess high specific surface area and large pore volume and has both large and fine pores. Therefore,active centres can be fully available.