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Fibre-optic fluorescing sensor for ammonia
Authors:Otto S Wolfbeis  Hermann E Posch
Institution:Institut für Organische Chemie, Karl-Franzens-Universität, A-8010 Graz Austria
Abstract:The fluorescing sensor is based on the change in fluorescence intensity of a buffered pH indicator solution entrapped in silicone rubber. Exposure to ammonia increases the pH of the trapped solution; this increases the fluorescence intensity, which is monitored via an optical fibre bundle. Ammonium chloride in 0.001 M sodium hydroxide, or the indicators themselves, can serve as buffers. Effects of sensor preparation and buffer composition on response time, reversibility and sensitivity are discussed.
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