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Occurrence of monoalkyllead species during the speciation of organolead
Authors:Rudy JA Van Cleuvenbergen  Dipankar Chakraborti  Fred C Adams
Institution:Department of Chemistry, University of Antwerp (U.I.A.), Universiteitsplein 1, B-2610 Wilrijk Belgium
Abstract:When tri-levels are determined in environmental samples by a method based on Grignard derivatization and subsequent gas chromatography/atomic absorption spectrometry, monoalkyllead species are sometimes detected. A rearrangement process during or following Grignard derivatization explains this occurrence at least partly. The accuracy of the determination does not suffer significantly from this limited-scale reaction but the detection of a monoalkyltributyllead species does not necessarily mean that the sample contains monoalkyllead compounds.
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