On-line application of ion chromatography in a thermal power plant |
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Authors: | L Balconi R Pascali F Sigon |
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Institution: | ENEL (Central Electricity Generating Board), Research and Development Division, Thermal and Nuclear Research Centre, Via Rubattino 54, Milano Italy |
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Abstract: | Complete monitoring of the “condensate-feedwater” cycle in power plants requires reliable automatic methods suitable for very low concentrations of various chemical species. A complete on-line ion-chromatography monitoring system is under development. It comprises an automatic on-line sampling system two Dionex Model QUIC (process instrument) ion chromatographs, an on-line calibration systems, and a data acquisition/processing system. The present model serves for the determination of sodium, chloride and sulfate ions. Detection limits are < 1 μg l?1 (P = 95%) with liner ranges up to 10 μ l?1 or about 200 μ l?1 depending on settings. The importance of statistical evaluation of data is emphasized. The instrumentation was tested for sequential samples from crucial points of a 320-MW thermal power station with satisfactory results. Problems of reliability are discussed. |
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