Polyfunctional Two- (2D) and Three- (3D) Dimensional Oxalate Bridged Bimetallic Magnets |
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| Authors: | René Clément Silvio Decurtins Michel Gruselle Cyrille Train |
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| Affiliation: | 1.Laboratoire de Chimie Inorganique, UMR-CNRS, 8613, Université Paris Sud, F-91405 Orsay Cedex, France,FR;2.Departement für Chemie und Biochemie, Universit?t Bern, Freiestrasse 3, CH-3012 Bern, Switzerland,CH;3.Laboratoire de Chimie Inorganique et Matériaux Moléculaires, CIM2 UMR-CNRS, 7071, Université Pierre et Marie Curie, 4 Place Jussieu, case 42, F-75252 Paris Cedex 05, France,FR |
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| Abstract: | Summary. We report major results concerning polyfunctional two- (2D) and three- (3D) dimensional oxalate bridged bimetallic magnets. As a consequence of their specific organisation they are composed of an anionic sub-lattice and a cationic counter-part. These bimetallic polymers can accommodate various counter-cations possessing specific physical properties in addition to the magnetic ones resulting from the interactions between the metallic ions in the anionic sub-lattice. Thus, molecular magnets possessing paramagnetic, conductive and optical properties are presented in this review. Corresponding author. E-mail: train@ccr.jussieu.fr Received April 11, 2002; accepted May 27, 2002 |
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| Keywords: | . Oxalate Molecular magnets NLO Photochromism Cotton effect Fluorescence. |
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