| 配合物Ni(C14H10N2O3)(C5H5N)的合成和晶体结构 |
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| 引用本文： | 卢文贯,刘宏文,冯小龙. 配合物Ni(C14H10N2O3)(C5H5N)的合成和晶体结构[J]. 无机化学学报, 2004, 20(12): 1493-1496 |
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| 作者姓名： | 卢文贯 刘宏文 冯小龙 |
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| 作者单位： | 1. 韶关学院化学系,韶关,512005
2. 中山大学分析测试中心,广州,510275 |
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| 摘 要： | A novel nickel(Ⅱ) complex with 2,4-dihydroxybenzalidene benzoylhydrazone and pyridine ligands, Ni(C14H10N2O3)(C5H5N), has been synthesized and characterized by elemental analysis and IR. The crystal structure of the title complex has been determined by single crystal X-ray diffraction techniques. The crystal belongs to orthorhombic, space group Pbca. The cell parameters are: a=1.580 20(19) nm, b=1.362 18(16) nm, c=1.616 50(19) nm, and V=3.479 5(7) nm3, Z=8, Dc=1.497 Mg·m-3, μ(MoKα)=1.139 mm-1, F(000)=1 616, R=0.032 9 and wR=0.077 0 for 2 772 observed reflections (I>2σ(I)) out of 3810 unique ones. The nickel(Ⅱ) ion lies in a distorted square-planar environment composed of two oxygen atoms, one nitrogen atom of tridentate acyhydrazone schiff base ligand and one nitrogen atom of the pyridine ligand. The analysis of the crystal structure indicates that the complex has a one-dimensional chain structure, which is formed by intermolecular hydrogen bonds. CCDC: 244668.
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| 关 键 词： | 酰腙 Schiff碱 镍(Ⅱ)配合物 晶体结构 一维链状结构 |
| 修稿时间： | 2004-06-02 |
Synthesis and Crystal Structure of Complex Ni(C14H10N2O3)(C5H5N) |
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| LU Wen-Guan,LIU Hong-Wen and FENG Xiao-Long. Synthesis and Crystal Structure of Complex Ni(C14H10N2O3)(C5H5N)[J]. Chinese Journal of Inorganic Chemistry, 2004, 20(12): 1493-1496 |
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| Authors: | LU Wen-Guan LIU Hong-Wen FENG Xiao-Long |
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| Affiliation: | Department of Chemistry, Shaoguan University, Shaoguan 512005,Department of Chemistry, Shaoguan University, Shaoguan 512005 and Center of Analysis and Measurement, Zhongshan University, Guangzhou 510275 |
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| Abstract: | |
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| Keywords: | Schiff base acyhydrazone nickel(II) complex crystal stru cture one-dimensional chain structure |
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