Mechanical behaviour of isotactic polypropylenes in the lower and the upper glass transitions ranges |
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Authors: | S Hellinckx |
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Institution: | (1) Solvay (LC604) Rue de Ransbeek 310 1120 Brussels, Belgium, BE |
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Abstract: | The effects of physical ageing on both glass transitions of isotactic polypropylenes (homopolymer and random copolymer)are
investigated by isothermal dynamic mechanical spectroscopy and by low strain creep. The ageing-time dependent expressions
of the amorphous fractions which undergo each relaxation are introduced in a rheological model composed by a modified Zener
model (associated to the β-relaxation) in series with a γ-element (associated to the α-relaxation). The agreement between
the responses of this model and the creep and dynamic results is good over a time (or frequency) range covering up to 15 decades
for three kinds of isotactic polypropylenes.
Received: 2 January 1996 Accepted: 16 August 1996 |
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Keywords: | Isotatic polypropylenes lower and upper glass transitions low strain creep dynamic mechanical spectroscopy physical ageing |
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