Special Chiral C2‐Symmetric endo‐Biarylnorbornane: Synthesis and Structure Illustration |
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| Authors: | Chonglin Cai Ruigang Chen Jun He Juntao Feng Xing Zhang |
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| Affiliation: | Research and Development Center of Biorational Pesticide, Northwest A&F University and Shaanxi Research Center of Biopesticide Engneering and Technology, YangLing, Shaanxi 712100, China |
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| Abstract: | A highly efficient and practical synthesis for strained special scaffold of chiral endo‐biarylnorbornane starting from available norbornadione was achieved with direct stereoselective dehydroxylation of tertiary alcohol as the key step, and the structure was illustrated by X‐ray structural analysis. |
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| Keywords: | endo‐biarylnorbornane stereoselective dehydroxylation synthesis design X‐ray diffraction chiral auxiliaries |
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