| RuO_2/TiO_2纳米薄膜的新构建及对CO_2的电催化还原 |
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| 引用本文： | 张莉娜,王金意,张涵轩,蔡文斌. RuO_2/TiO_2纳米薄膜的新构建及对CO_2的电催化还原[J]. 化学学报, 2010, 68(6): 590-593 |
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| 作者姓名： | 张莉娜 王金意 张涵轩 蔡文斌 |
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| 作者单位： | 复旦大学化学系上海分子催化与功能材料重点实验室,上海,200433;复旦大学化学系上海分子催化与功能材料重点实验室,上海,200433;复旦大学化学系上海分子催化与功能材料重点实验室,上海,200433;复旦大学化学系上海分子催化与功能材料重点实验室,上海,200433 |
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| 基金项目： | 国家自然科学基金(No. 20873031)资助项目;上海市基础研究(No.08JC1402000)重点项目 |
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| 摘 要： | 在旋涂有球状纳米TiO2薄膜的导电玻璃(ITO)基底上采用循环伏安法(CV)电沉积RuO2作为电催化还原CO2的阴极.采用场发射扫描电子显微镜(FE-SEM)表征了RuO2/TiO2纳米薄膜的形貌,并应用近稳态电位扫描法和计时电流法(i～t)研究了薄膜的电催化CO2性能.结果表明所构建的RuO2/TiO2薄膜中纳米粒子大小均匀、排列致密,且较传统热分解法所得催化剂有更好的电催化性能.
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| 关 键 词： | RuO_2/TiO_2纳米薄膜 循环伏安法 电还原CO_2 电催化 |
| 收稿时间： | 2009-07-25 |
| 修稿时间： | 2009-10-30 |
A Novel Fabrication of RuO_2/TiO_2 Nanofilms for Electrocatalytic Reduction of CO_2 |
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| Zhang Lina,Wang Jinyi,Zhang Hanxuan,Cai Wenbin. A Novel Fabrication of RuO_2/TiO_2 Nanofilms for Electrocatalytic Reduction of CO_2[J]. Acta Chimica Sinica, 2010, 68(6): 590-593 |
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| Authors: | Zhang Lina Wang Jinyi Zhang Hanxuan Cai Wenbin |
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| Affiliation: | (Shanghai Key Laboratory for Molecular Catalysis and Innovative Materials and Department of Chemistry, Fudan University, Shanghai 200433) |
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| Abstract: | RuO_2 electrodeposited on spherical-TiO_2 nanoparticles-spin-coated ITO substrate by using cyclic voltammetry (CV) was used as the cathode for electrocatalytic reduction of CO_2. The surface morphology of the as-prepared film was characterized by field emission scanning electron microscopy (FE-SEM) and its electrocatalytic performance was assessed by quasi-steady-state potentiodynamics and chronoamperometry (i～t). The results show that the as-prepared RuO_2/TiO_2 nanofilm consists of uniform and compact nanoparticles, exhibiting superior electrocatalytic activity and stability for electrochemical reduction of CO_2 as compared to that prepared by traditional thermal decomposition. |
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| Keywords: | RuO2/TiO2 nanofilms cyclic voltammetric deposition electroreduction of CO2 electrocatalysis |
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