| 两种固体荧光有机-无机杂化物的合成、结构及强红光发射 |
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| 引用本文： | 田悦,李飞,张国翠,周虹屏,吴杰颖,田玉鹏.两种固体荧光有机-无机杂化物的合成、结构及强红光发射[J].无机化学学报,2013,29(18). |
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| 作者姓名： | 田悦 李飞 张国翠 周虹屏 吴杰颖 田玉鹏 |
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| 作者单位： | 安徽大学无机功能材料化学重点实验室, 合肥 230601,安徽大学无机功能材料化学重点实验室, 合肥 230601,安徽大学无机功能材料化学重点实验室, 合肥 230601,安徽大学无机功能材料化学重点实验室, 合肥 230601,安徽大学无机功能材料化学重点实验室, 合肥 230601,安徽大学无机功能材料化学重点实验室, 合肥 230601;南京大学配位化学重点实验室, 南京 210093 |
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| 基金项目： | 国家自然科学基金（No.51372003，51432001，51472002，51672002）资助项目。 |
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| 摘 要： | 采用（E）-4-（4-（diphenylamino）styryl）-1-methylpyridinium iodide（DPASPI，DPASP=（E）-4-（4-（diphenylamino）styryl）-1-methylpyridi-nium），设计合成2种新型有机-无机杂化物（DPASP）2Zn（NCS）4]·2CH3OH （1）和{（DPASP）2Cd（SCN）（NCS）3]·2CH3OH}n （2）。通过单晶X射线衍射进行了表征，结果表明杂化物1和2是由有机吡啶阳离子和异硫氰酸金属配阴离子组成的，具有不同空间结构。通过1H NMR谱图解释了离子间相互作用。对具有高量子产率的杂化物1和2的红光发光性质进行了研究。
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| 关 键 词： | 有机-无机杂化物 大量高效合成 晶体结构 红光发射性质 |
| 收稿时间： | 2016/9/1 0:00:00 |
| 修稿时间： | 2016/12/26 0:00:00 |
Two Solid Fluorescent Organic-Inorganic Hybrids: Synthesis,Crystal Structures and Strong Red Fluorescence Emissions |
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| TIAN Yue,LI Fei,ZHANG Guo-Cui,ZHOU Hong-Ping,WU Jie-Ying and TIAN Yu-Peng.Two Solid Fluorescent Organic-Inorganic Hybrids: Synthesis,Crystal Structures and Strong Red Fluorescence Emissions[J].Chinese Journal of Inorganic Chemistry,2013,29(18). |
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| Authors: | TIAN Yue LI Fei ZHANG Guo-Cui ZHOU Hong-Ping WU Jie-Ying and TIAN Yu-Peng |
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| Institution: | Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China,Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China,Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China,Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China,Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China and Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China |
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| Abstract: | Two organic-inorganic hybrids,(DPASP)2Zn (NCS)4]·2CH3OH (1) and{(DPASP)2Cd (SCN)(NCS)3]·2CH3OH}n (2),have been facilely prepared from (E)-4-(4-(diphenylamino) styryl)-1-methylpyridinium iodide (DPASPI,DPASP=(E)-4-(4-(diphenylamino) styryl)-1-methylpyridinium) at gram scale.Their crystal structures have been confirmed by single-crystal X-ray diffraction analysis,which show that the hybrids 1 and 2 consist of organic pyridium cations and metal thiocyanato anions bearing different spacial structure through self-assembly processes.Furthermore,the interactions between the ions have been investigated by 1H NMR spectra.Finally,red photolumencent properties with enhanced quantum yields of hybrids 1 and 2 were investigated.CCDC:1517533,1;1060372,2. |
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| Keywords: | organic-inorganic hybrid scalable efficient synthesis crystal structure red photoluminescent property |
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