| First Synthesis of Mosquito Larvicidal Butenolides I and Ⅱ |
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| 引用本文： | JIANG,Sheng WU，Yu－Lin 等. First Synthesis of Mosquito Larvicidal Butenolides I and Ⅱ[J]. 中国化学, 2002, 20(7): 692-696. DOI: 10.1002/cjoc.20020200713 |
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| 作者姓名： | JIANG Sheng WU，Yu－Lin 等 |
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| 作者单位： | [1]StateKeyLaboratoryofBioorganic＆NaturalProductsChemistry,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai200032 [2]StateKeyLaboratoryofBioorganic＆NaturalProductsChemistry,ShanghaiInst |
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| 摘 要： | Utilizing aldol condensation and β-elimiation as the key steps,butenolides I and Ⅱ in excellent enantiomeric purity have been concisely synthesized for the first time.According to the ratation difference between synthetic samples and natural products,the rotations were corrected by the calculation upon HPLC measurements.In addition,an efficient way to synthesize methyl pentadec-14-enoate was developed.
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| 关 键 词： | 合成 蚊子 杀幼虫剂 丁烯羟酸内酯 |
First Synthesis of Mosquito Larvicidal Butenolides I and II |
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| Sheng Jiang,Yu‐Lin Wu,Zhu‐Jim Yao. First Synthesis of Mosquito Larvicidal Butenolides I and II[J]. Chinese Journal of Chemistry, 2002, 20(7): 692-696. DOI: 10.1002/cjoc.20020200713 |
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| Authors: | Sheng Jiang Yu‐Lin Wu Zhu‐Jim Yao |
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| Abstract: | Utilizing aldol condensation and β‐elimination as the key steps, butenolides I and II in excellent enantiomeric purity have been concisely synthesized for the first time. According to the rotation difference between synthetic samples and natural products, the rotations were corrected by the calculation upon HPLC measurements. In addition, an efficient way to synthesize methyl pentadec‐14‐enoate was developed. |
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| Keywords: | butenolides I and II aldol condensation methyl pentadec‐14‐enoate |
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