Thermometry of an oxy-acetylene flame using multiplex degenerate four-wave mixing of C2

Thermometry of an oxy-acetylene flame using multiplex Degenerate Four-Wave Mixing (DFWM) of C₂ is demonstrated. More than 100 rotational transitions in thed³_g a³_u (0,0) Swan band of C₂ could be recorded simultaneously by use of a pulsed, broad bandwidth modeless laser. Temperatures were inferred by fitting temperature-dependent synthetic spectra of single- or multiple-shot averaged spectra. The strength and reliability of recorded signals together with the large number of rotational lines observed suggest that multiplex DFWM is a promising technique for minor species detection and for temporally resolved temperature measurements in luminous environments. Factors influencing the accuracy and precision of single-shot thermometry using the technique are discussed.