Study of electron donor-acceptor complexes of tri-n-octyl amine with [60]- and [70]fullerenes and some other electron acceptors by absorption spectrophotometric method

Electron donor-acceptor (EDA) complexes of tri-n-octylamine (TOA) with 60]- and 70]fullerenes and some other electron acceptors have been studied in chloroform medium by absorption spectrophotometric technique. Charge transfer (CT) absorption bands are observed in the visible region. Vertical ionization potential of TOA was determined utilizing CT transition energy. Oscillator strengths, transition dipole strengths and resonance energies for all the complexes have been calculated. 60]Fullerene/TOA and 70]fullerene/TOA complexes are found to decay slowly with time. Kinetics of these reactions have been studied and activation energies for such processes have been estimated. Ab initio calculations suggest that complexation of 70]fullerene with TOA is enthalpy favoured.