The reactions of 2-vinylnaphthalene and 4-vinylbiphenyl with the benzoyloxy radical |
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| Institution: | 1. Department of Chemical Engineering, Monash University, Clayton, 3800, Australia;2. Chemical Engineering Innovation Laboratory, College of Chemistry, Chemical Engineering and Material Science, Soochow University, Suzhou, Jiangsu Province, China;1. Amrita Vishwa Vidyapeetham, Amrita University, Coimbatore, India;2. Mahatma Gandhi University, Kottayam, India;3. Indian Institute of Space Science and Technology, Thiruvananthapuram, India;1. National Engineering Research Center for Marine Aquaculture, Institute of Innovation & Application, Zhejiang Ocean University, Zhoushan 316022, China;2. State Key Laboratory of Southwestern Chinese Medicine Resources, School of Pharmacy, Chengdu University of Traditional Chinese Medicine, Chengdu 611137, China;3. Department of Chemical Engineering, Waterloo Institute for Nanotechnology, University of Waterloo, Waterloo, ON N2L3G1, Canada;4. Macau Centre for Research and Development in Chinese Medicine, Institute of Chinese Medical Sciences, University of Macau, Macao 999078, China |
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| Abstract: | Benzoyl peroxide, labelled with carbon-14 and tritium, has been used to initiate polymerizations of 2-vinylnaphthalene and 4-vinylbiphenyl. The numbers of benzoate and phenyl end-groups in the polymers have been compared. The results have been used for study of the competition between decarboxylation of the benzoyloxy radical and its reaction with monomer. Both monomers are appreciably more reactive than styrene towards the radical. |
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