Influence of the texture of the polymer support on the kinetics of reduction by supported borohydride |
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| Affiliation: | 1. Department of Chemistry, Yazd University, Yazd, Iran;2. Department of Chemistry, Jiroft University, Jiroft, Iran;1. Department of Food Science, Nutrition and Health Promotion, Mississippi State University, Mississippi State, MS 39762, USA;2. Poultry Science Department, Mississippi State University, Mississippi State, MS 39762, USA |
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| Abstract: | The influence of the texture of the polymer support on the kinetics of reduction by supported borohydride is examined. The polymer supports are obtained by chemical modification of styrene/DVB copolymers (chloromethylation and amination). We have shown that the kinetics depend on the texture of the polymeric support. This dependence is explained by the site accessibility which depends on three parameters, viz. surface area, pore volume and crosslinking degree. |
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