Syntheses on the basis of 2H-chromen-2-one and 2H-chromene-2-thione |
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Authors: | A A Avetisyan A G Alvandzhyan |
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Institution: | (1) Erevan State University, ul. A. Manukyana 1, Erevan, 375025, Armenia |
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Abstract: | 4-Hydroxy-2H-chromen-2-one and 4-hydroxy-2H-chromene-2-thione reacted with allyl bromide, 1,1,3-trichloroprop-1-ene, and 1,3-dichlorobut-2-ene to give the corresponding ethers, which were oxidized to (2-oxo-2H-chromen-4-yloxy)acetic acid with potassium permanganate, and various derivatives of that acid were obtained. 3-(3,3-Dichloroprop-2-enyl)-7-hydroxy-4-methyl-2H-chromen-2-one and 3-(3,3-dichloroprop-2-enyl)-7-hydroxy-4-methyl-2H-chromene-2-thione were synthesized, and some their transformations were studied. |
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