| Formation, Isolation and Characterization of a New Ruthenium Complex in Reaction of Acetone Masked Terminal Alkynone with Transfer Hydrogenation Catalyst |
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| 作者姓名： | 郭敏捷 李到 孙延辉 成江 张兆国 |
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| 作者单位： | [1]StateKeyLaboratoryofOrganometallics,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai200032,China [2]DepartmentofChemistry,NanjingUniversity,Nanjing,Jiangsu210093,China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China (No. 20172067)，the Chinese Academy of Sciences，and the Shanghai Mu-nicipal Commission of Science and Technology. |
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| 摘 要： | Reaction of 1S,2S-(Ts-diphen)Ru(Ⅱ)(p-cymene)] (1S,2S-Ts-diphen= 1S,2S-N-tosyl-1,2-diphenylethylenediamine) and 2-hydroxy-2-methyl-non-3-yn-5-one under transfer hydrogenation condition gave a ruthenium complex bearing a 2,5-dihydrofuran moiety. The complex was characterized and a possible mechanism for the formation of the complex was proposed.
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| 关 键 词： | 分离 表征 钌配合物 丙酮 烷基酮 加氢催化 炔 二羟基呋喃 |
Formation, Isolation and Characterization of a New Ruthenium Complex in Reaction of Acetone Masked Terminal Alkynone with Transfer Hydrogenation Catalyst |
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| GUO,Min-Jiea LI,Daoa SUN,Yan-Huib CHENG,Jiangb ZHANG,Zhao-Guo,a State Key Laboratory of Organometallics.Formation, Isolation and Characterization of a New Ruthenium Complex in Reaction of Acetone Masked Terminal Alkynone with Transfer Hydrogenation Catalyst[J].Chinese Journal of Chemistry,2004,22(12):1413-1416. |
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| Authors: | GUO Min-Jiea LI Daoa SUN Yan-Huib CHENG Jiangb ZHANG Zhao-Guo a State Key Laboratory of Organometallics |
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| Institution: | GUO,Min-Jiea LI,Daoa SUN,Yan-Huib CHENG,Jiangb ZHANG,Zhao-Guo*,a State Key Laboratory of Organometallics,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China b Department of Chemistry,Nanjing University,Nanjing,Jiangsu 210093,China |
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| Abstract: | Reaction of 1S,2S-(Ts-diphen)Ru(II)(p-cymene)] (1S,2S-Ts-diphen=1S,2S-N-tosyl-1,2-diphenylethylenedi- amine) and 2-hydroxy-2-methyl-non-3-yn-5-one under transfer hydrogenation condition gave a ruthenium complex bearing a 2,5-dihydrofuran moiety. The complex was characterized and a possible mechanism for the formation of the complex was proposed. |
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| Keywords: | ruthenium transfer hydrogenation alkyne alkynone dihydrofuran |
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