Correlation between atomic orientation and product angular momentum alignment in the reaction of oriented Ar (3P2) with CH3OH |
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Authors: | Ohoyama H Matsumura T Yasuda K Watanabe D Kasai T |
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Affiliation: | Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. |
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Abstract: | Atomic orientation effect for the CH(3)O(*) formation has been studied for the dissociative energy transfer reaction of oriented Ar ((3)P(2)) with CH(3)OH. The degree of polarization of CH(3)O(*) chemiluminescence was determined as a function of each magnetic M(J) (') substate in the collision frame. A drastic change of the product angular momentum alignment due to atomic orientation was recognized. |
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