| 三核钼原子簇化合物的研究进展 |
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| 引用本文： | 黄金陵,商茂虞,黄建全.三核钼原子簇化合物的研究进展[J].有机化学,1983,3(5):325-335. |
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| 作者姓名： | 黄金陵 商茂虞 黄建全 |
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| 作者单位： | 中国科学院福建物质结构研究所，中国科学院福建物质结构研究所，福州大学化学化工系 |
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| 摘 要： | 本文结合作者等人的研究工作,总结了迄今文献上所发表的成果,包括三核钼原子簇化台物的各种合成方法,结构类型,并用简化的量子化学方法对几种主要结构类型簇胳的金属-金属键加以分析。在这基础上,对几种主要性质加以讨论。
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| 关 键 词： | 综述 簇状化合物 钼络合物 多核络合物 制备 金属键 |
Progress in Research on Trinuclear Molybdenum Clusters |
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| Huang Jinling,Shang Maoyu Fujian Institute of Research on the Structure of Matter,Academia Sinica Huang Jianquan.Progress in Research on Trinuclear Molybdenum Clusters[J].Chinese Journal of Organic Chemistry,1983,3(5):325-335. |
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| Authors: | Huang Jinling Shang Maoyu Fujian Institute of Research on the Structure of Matter Academia Sinica Huang Jianquan |
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| Institution: | Huang Jinling,Shang Maoyu Fujian Institute of Research on the Structure of Matter,Academia Sinica Huang Jianquan Department of Chemistry,Fuzhou University |
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| Abstract: | This Paper summarizes the recent research work on trinuclear molybde-num clusters,including those published in literatures and results obtained by the authors.The first part of it is concerned with the methods used to synthesize the cluster com-pounds.The second part describes the different types of the configurations of trinuclearMo clusters.The third part is analyses the bonding characteristics of the metal-metalbonds for three main types of structure skeletons by the quantum chemistry method.Onthis basis,some main properties are given. |
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| Keywords: | review cluster compound molybdenum complex polynuclear complex preparation metallic bonds |
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