| High Photocatalytic Properties of Zinc OxideNanoparticles with Amidoximated BacterialCellulose Nanofibers as Templates简 |
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| 引用本文： | 陈仕艳,王华平. High Photocatalytic Properties of Zinc OxideNanoparticles with Amidoximated BacterialCellulose Nanofibers as Templates简[J]. 高分子科学, 2014, 32(2): 169-176. DOI: 10.1007/s10118-014-1386-0 |
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| 作者姓名： | 陈仕艳 王华平 |
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| 基金项目： | This work was financially supported by the Program of Introducing Talents of Discipline to Universities （B07024）, Shanghai Leading Academic Discipline Project （B603）, The National Natural Science Foundation of China （No. 51273043） and Project of the Action on Scientists and Engineers to Serve Enterprises （2009GJE20016）. |
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| 摘 要： | The freshly prepared water-wet amidoximated bacterial cellulose （Am-BC） serves as an effective nanoreactor to synthesis zinc oxide nanoparticles by in situ polyol method. The obtained ZnO/Am-BC nanocomposites have been characterized by field emission scanning electron microscopy （FE-SEM）, X-ray diffraction （XRD）, Fourier transformed infrared spectroscopy （FTIR） and thermogravimetric analysis （TGA）. The influence of the zinc acetate concentration on the morphologies and size ofZnO nanoparticles and the possible formation mechanism were discussed. The results indicated that uniform ZnO nanoparticles were homogeneously anchored on the Am-BC nanofibers through strong interaction between the hydroxyl and amino groups of Am-BC and ZnO nanoparticles. The loading content of ZnO nanoparticles is higher using Am-BC as a template than using the unmodified bacterial cellulose. The resultant nanocomposite synthesized at 0.05 wt% shows a high photocatalytic activity （92%） in the degradation of methyl orange.
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| 关 键 词： | 氧化锌纳米颗粒 ZnO纳米粒子 细菌纤维素 纳米纤维 光催化性能 模板 傅里叶变换红外光谱 纳米复合材料 |
High photocatalytic properties of zinc oxide nanoparticles with amidoximated bacterial cellulose nanofibers as templates |
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| Wei-li Zheng,Wei-li Hu,Shi-yan Chen,Yi Zheng,Bi-hui Zhou,Hua-ping Wang. High photocatalytic properties of zinc oxide nanoparticles with amidoximated bacterial cellulose nanofibers as templates[J]. Chinese Journal of Polymer Science, 2014, 32(2): 169-176. DOI: 10.1007/s10118-014-1386-0 |
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| Authors: | Wei-li Zheng Wei-li Hu Shi-yan Chen Yi Zheng Bi-hui Zhou Hua-ping Wang |
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| Affiliation: | 1. Key Laboratory of High Performance Fibers and Products of Ministry of Education, State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620, China
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| Abstract: | The freshly prepared water-wet amidoximated bacterial cellulose (Am-BC) serves as an effective nanoreactor to synthesis zinc oxide nanoparticles by in situ polyol method. The obtained ZnO/Am-BC nanocomposites have been characterized by field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), Fourier transformed infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). The influence of the zinc acetate concentration on the morphologies and size of ZnO nanoparticles and the possible formation mechanism were discussed. The results indicated that uniform ZnO nanoparticles were homogeneously anchored on the Am-BC nanofibers through strong interaction between the hydroxyl and amino groups of Am-BC and ZnO nanoparticles. The loading content of ZnO nanoparticles is higher using Am-BC as a template than using the unmodified bacterial cellulose. The resultant nanocomposite synthesized at 0.05 wt% shows a high photocatalytic activity (92%) in the degradation of methyl orange. |
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| Keywords: | Amidoximated bacterial cellulose Nanoreactor ZnO nanoparticles High photocatalytic activity. |
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