MOF-derived ZnCo2O4/C wrapped on carbon fiber as anode materials for structural lithium-ion batteries |
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Authors: | Huagen Li Shubin Wang Mengjie Feng Jiping Yang Boming Zhang |
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Institution: | Key Laboratory of Aerospace Materials and Performance, School of Materials Science and Engineering, Beihang University, Beijing 100191, China |
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Abstract: | To meet the requirements for the mechanical and electrochemical performance for carbon fiber-based (CF-based) composites in the structural lithium ion batteries (SLIBs) application, better CF-Based composites are urgently needed. Herein, we report a novel composite metal organic framework (MOF)-derived ZnCo2O4/C@carbon fiber via a facile method and subsequent annealing treatment. In this anode, the nano ZnCo2O4/C coatings wrapped on the surface of CF provide more active sites for electrode reactions and the thin carbon layers give the additional protection. For this material, after 100 cycles, it exhibits excellent cycling stability including high reversible capacity of 463 mA h/g at 50 mA/g, which increases 201% than that of the CF. Thus, this structural anode material exhibits enhanced capacity, high initial columbic efficiency. |
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Keywords: | Carbon fiber-based composite Structural lithium ion batteries Metal organic framework High reversible capacity Cycling stability |
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