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A thermodynamic framework for a mixture of two liquids
Authors:J Mlek  KR Rajagopal
Institution:aCharles University, Faculty of Mathematics and Physics, Mathematical Institute, Sokolovská 83, 186 75 Prague 8, Czech Republic;bDepartment of Mechanical Engineering, Texas A&M University, College Station, TX 77843, USA
Abstract:In this study, we extend a thermodynamic framework that has been used with some success for describing the response of a variety of single constituent continua. Using the thermodynamic framework, we obtain a model for the mixture of two compressible fluids that has a much simpler structure than the model obtained earlier within the context of mixture theory. We also investigate the response of a mixture of two fluids that is constrained to have a constant volume, using the same thermodynamic framework.
Keywords:Mixture  Internal energy  Helmholtz potential  Rate of dissipation  Maximization and rate of entropy production
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