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THE SPATIAL DISTRIBUTION AND MOMENTS OF CIRCULAR FREELY JOINTED CHAIN
引用本文:郝鸣鸿. THE SPATIAL DISTRIBUTION AND MOMENTS OF CIRCULAR FREELY JOINTED CHAIN[J]. 高分子科学, 1991, 0(2): 101-107
作者姓名:郝鸣鸿
作者单位:Institute of
摘    要:The spatial distribution function and second moments of circular freely jointed chain are derived based on an analytical method. The circular Gauss chain, which is simple for long chains, is compared with the circular freely jointed chain, which is exact for short chains. It is shown that the Gauss chain model predicts a more compact configurational distribution than the exact freely jointed chain. The two chain models, however, become closer to each other when the chain length increases. It is found that the difference of the mean square radius of gyration calculated with these two chain models is a constant, independent of the chain length.

收稿时间:1989-06-30

THE SPATIAL DISTRIBUTION AND MOMENTS OF CIRCULAR FREELY JOINTED CHAIN
HAO Minghong. THE SPATIAL DISTRIBUTION AND MOMENTS OF CIRCULAR FREELY JOINTED CHAIN[J]. Chinese Journal of Polymer Science, 1991, 0(2): 101-107
Authors:HAO Minghong
Affiliation:Institute of Molecular Science; Shanxi University; Taiyuan; Shanxi
Abstract:The spatial distribution function and second moments of circular freely jointed chain are derived based on an analytical method. The circular Gauss chain, which is simple for long chains, is compared with the circular freely jointed chain, which is exact for short chains. It is shown that the Gauss chain model predicts a more compact configurational distribution than the exact freely jointed chain. The two chain models, however, become closer to each other when the chain length increases. It is found that the difference of the mean square radius of gyration calculated with these two chain models is a constant, independent of the chain length.
Keywords:Freely Jointed Chain  Gauss Chain  Spatial Distribution
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