The mechanism of photooxidation of the menaquinones |
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| Authors: | David Creed Harold Werbin Tom Daniel |
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| Affiliation: | Department of Chemistry, University of Southern Mississippi, Hattiesburg, Mississippi 39401 USA;Molecular Biology Programs, University of Texas at Dallas, Richardson, Texas 75080 USA |
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| Abstract: | Irradiation of menaquinone-1 under nitrogen gives rise to metastable isomeric o-quinone methides, one of which reacts with oxygen in the dark to form the same hydroperoxide obtained previously from direct or dye sensitized photolysis of the quinone in the presence of oxygen. |
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