The intramolecular Diels-Alder reaction: Stereocontrol through nonsynchronous bond formation? |
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Authors: | Douglass P Taber Carlton Campbell Bruce P Gunn I-Ching Chiu |
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Institution: | Department of Pharmacology School of Medicine Vanderbilt University Nashville, Tennessee 37232 U.S.A. |
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Abstract: | Nonsynchronous bond formation in the transition state of the intramolecular Diels-Alder reaction is suggested to be an important determinant of the stereochemical outcome of the cyclization. |
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