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The intramolecular Diels-Alder reaction: Stereocontrol through nonsynchronous bond formation?
Authors:Douglass P Taber  Carlton Campbell  Bruce P Gunn  I-Ching Chiu
Institution:Department of Pharmacology School of Medicine Vanderbilt University Nashville, Tennessee 37232 U.S.A.
Abstract:Nonsynchronous bond formation in the transition state of the intramolecular Diels-Alder reaction is suggested to be an important determinant of the stereochemical outcome of the cyclization.
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