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Reaction of chloromethylcarbene with trimethylsilyl enol ethers. Synthesis of eucarvone, (±)-nuciferal and (±)-manicone.
Authors:L Blanco  N Slougui  G Rousseau  JM Conia
Abstract:New synthesis of Eucarvone 7, (±)-Nuciferal 12 and (±)-Manicone 16 are described from trimethylsilyl enol ethers 2, 10 and 14 via their chloromethylenation products by means of a two carbons homologation reaction.
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