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Lewis acid mediated allylation of 2-alkanoyl-1,4-quinones with allylsilane and allylstannane
Authors:Yoshinori Naruta  Hidemitsu Uno  Kazuhiro Maruyama
Institution:Department of Chemistry, Faculty of Science, Kyoto University, Kyoto, 606 Japan
Abstract:Allyltrimethylstannane reacts uith 2-alkanoyl-1,4-quinones regioselectively to afford conjugate addition products which can be derived to 2-alkanoyl- 3-allylhydroquinone diacetate, while allyltriphenylsilane reacts with the quinone to give naphthofuran.
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