Lewis acid mediated allylation of 2-alkanoyl-1,4-quinones with allylsilane and allylstannane |
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Authors: | Yoshinori Naruta Hidemitsu Uno Kazuhiro Maruyama |
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Institution: | Department of Chemistry, Faculty of Science, Kyoto University, Kyoto, 606 Japan |
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Abstract: | Allyltrimethylstannane reacts uith 2-alkanoyl-1,4-quinones regioselectively to afford conjugate addition products which can be derived to 2-alkanoyl- 3-allylhydroquinone diacetate, while allyltriphenylsilane reacts with the quinone to give naphthofuran. |
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