Electron-transfer chain-substitution in hydrodemercuration of alkylmercury(II) compounds with n-benzyl-1,4-dihydronicotinamide |
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| Authors: | Hideo Kurosawa Hiroshi Okada Tatsuaki Hattori |
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| Affiliation: | Department of Petroleum Chemistry, Osaka University, Yamadaoka, Suita, Osaka 565, Japan |
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| Abstract: | Reduction of alkylmercury(II) acetates with N-benzyl-1,4-dihydronicotinamide (BNAH) proceeds through electron-transfer chain-substitution mechanism. The rate constant of hydrogen transfer from BNAH to alkyl radical was estimated as in the order of 105 1/mol·sec. |
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