Phosphorus heterocycle synthesis by RPX2,· AlX3 addition to [1,n]dienes VII. |
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Authors: | Y Kashman A Rudi |
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Institution: | Department of Chemistry, Tel-Aviv University, Ramat Aviv 69978, Israel |
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Abstract: | The RPX2·AlX3 complex () reacts with unsaturated ketones and imines to give novel 7-oxa and 7-aza-2-phosphabicyclo2.2.1]heptanes (compounds and respectively).A new 1,3-dipolar addition of (CH3)2 CCH2P?XR to nArN=C=S was disclosed resulting in the formation of the 2-imino-1,3-thiaphospholanes (). |
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