Umpolung of reactivity of allylsilane,allylgermane, and allylstannane via their reaction with thallium (III) salt: a new allylation reaction for aromatic compound |
| |
Authors: | Masahito Ochiai Masao Arimoto Eiichi Fujita |
| |
Affiliation: | Institute for Chemical Research, Kyoto University, Uji, Kyoto-Fu 611, Japan |
| |
Abstract: | A new direct allylation of the aromatic compound has been developed. A combination of allylsilane, allylgermane, or allylstannane and thallium (III) trifluoroacetate gave rise to an allyl cationic species which was allowed to react with an aromatic compound, a nucleophile, to give allylation product(s) in good yields. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|