Umpolung of reactivity of allylsilane,allylgermane, and allylstannane via their reaction with thallium (III) salt: a new allylation reaction for aromatic compound |
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| Authors: | Masahito Ochiai Masao Arimoto Eiichi Fujita |
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| Institution: | Institute for Chemical Research, Kyoto University, Uji, Kyoto-Fu 611, Japan |
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| Abstract: | A new direct allylation of the aromatic compound has been developed. A combination of allylsilane, allylgermane, or allylstannane and thallium (III) trifluoroacetate gave rise to an allyl cationic species which was allowed to react with an aromatic compound, a nucleophile, to give allylation product(s) in good yields. |
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