Preparation of 4-hydroxy-2-alkenenitriles from phrnylsulfinylacetonitrile with keetones or aldehydes,and its synthetic application to substituted furans |
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| Authors: | J. Nokami T. Mandai Y. Imakura K. Nishiuchi M. Kawada S. Wakabayashi |
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| Affiliation: | Okayama University of Science, Ridai, Okayama, 700 Japan |
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| Abstract: | The reaction of phenylsulfinylacetonitrile 1 with ketones or aldehydes gave 4-hydroxy-2-alkenenitriles which were converted to 2- and/or 3-substituted furans by the treatment with diisobutylaluminumhydride(DIBAL) followed by acid hydrolysis. |
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