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α-Hydroxylation of ketones: Osmium tetroxide/N-methylmorpholine-N-oxide oxidation of silyl enol ethers |
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| Authors: | JP McCormick Witold Tomasik Mark W Johnson |
| Institution: | Department of Chemistry, University of Missouri, Columbia, Missouri 65211 U.S.A. |
| Abstract: | Osmium tetroxide/N-methylmorpholine-N-oxide oxidation of silyl enol ethers, derived from ketones with either kinetic or thermodynamic regiochemical control, produces α-ketols in good to excellent yields. |
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