| Synthesis and Characterization of Binuclear Lanthanide Complexes with Macrocyclic Schiff Base Derived From 2,6-Diacetylpyridine and 1,3-Diamino-2-hydroxypropane |
| |
| 作者姓名： | ZHENG Hui YAN Shi-ping CHENG Peng LIAO Dai-zhengJIANG Zong-hui and WANG Geng-lin |
| |
| 作者单位： | Department of Chemistry，Nankai University，Tianjin，300071 |
| |
| 基金项目： | Supported by the National Natural Science Foundation of China |
| |
| 摘 要： | Nine homobinuclear lanthanide complexes with macrocyclic Schiff base were prepared by condensing 2, 6-diacetylpyridine and 1, 3-diamino-2-hydroxypropane in the presence of template lanthanide metal ions. These complexes were characterized by elemental analysis, IR, molar conductance and magnetic susceptibility. The variable-temperature magnetic susceptibility (4-300 K) of complexes of Gd( Ⅲ ) and Dy( Ⅲ ) was determined. A satisfactory fit to theoretical curve derived from spin Hamiltonian operator was obtained using least-squares method. The exchange interaction parameters are J=-0.26 cm-1, g=1.98 and △=0.06 cm-1, Z.J'=-0. 21 cm-1,g'=1.33 for Gd( Ⅲ ) and Dy( Ⅲ ), respectively. The results indicate a very week antiferromagnetic interaction between Gd( Ⅲ )-Gd( Ⅲ ) and Dy( Ⅲ )-Dy( Ⅲ ) ions.
|
Synthesis and Characterization of Binuclear Lanthanide Complexes with Macrocyclic Schiff Base Derived From 2,6-Diacetylpyridine and 1,3-Diamino-2-hydroxypropane |
| |
| ZHENG Hui,YAN Shi-ping,CHENG Peng,LIAO Dai-zhengJIANG Zong-hui and WANG Geng-lin.Synthesis and Characterization of Binuclear Lanthanide Complexes with Macrocyclic Schiff Base Derived From 2,6-Diacetylpyridine and 1,3-Diamino-2-hydroxypropane[J].Chemical Research in Chinese University,1993(3). |
| |
| Authors: | ZHENG Hui YAN Shi-ping CHENG Peng LIAO Dai-zhengJIANG Zong-hui and WANG Geng-lin |
| |
| Abstract: | |
| |
| Keywords: | Binuclear complex Macrocyclic complex Lanthanide Magnetism |
| 本文献已被 CNKI 等数据库收录！ |
