Online electrothermal heating of laser-generated aerosols: effects on aerosol particle size and signal intensities in ICPMS |
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Authors: | Brogioli Robert Hattendorf Bodo Koch Joachim Wiltsche Helmar Flamigni Luca Günther Detlef |
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Institution: | (1) Laboratory of Inorganic Chemistry, ETH Zurich, Wolfgang-Pauli Strasse 10, 8093 Zurich, Switzerland;(2) Institute for Analytical Chemistry and Food Chemistry, Graz University of Technology, Stremayrgasse 9, 8010 Graz, Austria; |
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Abstract: | To achieve separation of isobaric interferences and minimization of matrix related interferences for laser ablation-inductively
coupled plasma mass spectrometry (LA-ICPMS) electrothermal heating of laser generated aerosols was investigated by analyzing
a range of solid samples: NIST SRM 610, MBH B26, BAM M381, BAM M601 and Tantalum. ICPMS measurements showed that individual
elements can be removed from the laser-generated aerosol at characteristic temperatures for different solid materials. Signal
reduction as high as 3 orders of magnitude were achieved for volatile elements, such as Ag and Cd when heating laser-generated
aerosol of NIST SRM 610 silicate glass. A signal reduction of more than 99% was obtained for Rb while Sr remained practically
unaffected. A temperature- and matrix-dependent change of particle size distribution after aerosol heating was observed by
means of laser light scattering (direct aerosol visualization) and scanning electron microscopy. In the temperature range
between 900 and 1,200 °C, element unspecific signal suppression was observed, which could be related to a change of the particle
size distributions. |
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