Comparison of stationary phases for packed column supercritical fluid chromatography based upon ionic liquid motifs: a study of cation and anion effects |
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Authors: | Jonathan Smuts Eranda Wanigasekara Daniel W Armstrong |
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Institution: | (1) Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, TX 76019, USA; |
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Abstract: | A class of stationary phases for packed column supercritical fluid chromatography (SFC), referred to as immobilized ionic
liquids (IILs), is evaluated with a two-part study: (1) a cation effect study and (2) an anion effect study. The former study
compares six different IILs (tripropylphosphonium, tributylphosphonium, methyl-imidazolium, benzyl-imidazolium, triphenylphosphonium,
and 4,4′-bipyridyl) on silica gel, evaluating their performance in SFC with all the counter anions as trifluoroacetate (TFA−). In the latter study, the stationary phase consisted of a bonded tributylphosphonium cation and varying counter anions (acetate,
TFA−, chloride, NTf2−, and perchlorate). An order of retentivity was established for the cation effect study, and the favorable behavior of phosphonium-based
stationary phases is reported for the first time in SFC. It was not possible to always assign a retentivity order for the
anion effect study, but wide variations in selectivity are noted for different anions showing the tunable nature of this class
of stationary phases. |
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