Facile formation of molybdenum(VI) monooxo aryloxides MoO(OAr)4-nCln from molybdenum dioxo dichloride |
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| Authors: | Hanna Tracy A Ghosh Amit K Ibarra Catalina Zakharov Lev N Rheingold Arnold L Watson William H |
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| Institution: | Department of Chemistry, Texas Christian University, Box 298860, Fort Worth, Texas 76129, USA. t.hanna@tcu.edu |
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| Abstract: | Molybdenum monooxo compoundsMoO(OAr)4-nCln (n=0-2, Ar=2,6-Me2C6H3 or 2,6-i-Pr2C6H3) have been synthesized starting from the dioxo precursor MoO2Cl2. The complexes are characterized spectroscopically and by X-ray diffraction. The formation mechanism likely involves phenol precoordination followed by addition across the Mo=O bond. |
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