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Kinetic Model of the PTC Aminolysis of 4-Nitrophenyl Acetate with Solid Potassium Glycinate |
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| Authors: | Vakhitova L N Savelova V A Burdina Ya F Belousova I A Popov A F |
| Institution: | (1) L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 R. Luxemburg Vul., 83114, Donets'k, Ukraine |
| Abstract: | A mechanism of phase-transfer catalysis in a solid/liquid system was proposed during akinetic investigation of the aminolysis of 4-nitrophenyl acetate with solid potassium glycinate in chlorobenzene in the presence of 18-crown-6. The quantitative parameters were determined for all the stages of the catalytic cycle, including the distribution of the reagents between the phases and the chemical reactions that occur. |
| Keywords: | phase-transfer catalysis solid phase |
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