| MgSO4·5Mg(OH)2·3H2O的水热合成及反应时间对其形貌的影响 |
| |
| 引用本文： | 朱黎霞,岳涛,高世扬,夏树屏. MgSO4·5Mg(OH)2·3H2O的水热合成及反应时间对其形貌的影响[J]. 无机化学学报, 2003, 19(1): 99-102 |
| |
| 作者姓名： | 朱黎霞 岳涛 高世扬 夏树屏 |
| |
| 作者单位： | 中国科学院青海盐湖研究所西安二部，西安 710043,兰州大学化学系，兰州 730000,中国科学院青海盐湖研究所西安二部，西安 710043;陕西师范大学应用化学研究所，西安 710069,中国科学院青海盐湖研究所西安二部，西安 710043 |
| |
| 摘 要： | Both whisker and nanometer MgSO4·5Mg(OH)2·3H2O(MOS) were prepared by hydrothermal method at 140℃ for different times， using NaOH and MgSO4·7H2O as raw materials. The MgSO4·5Mg(OH)2·3H2O part- icles were characterized by powder X-ray diffraction(XRD)，thermal analysis(TGA-DSC)， infrared spectroscopy(FT-IR)，transmission electron microscopy(SEM) and scanning electron microscopy(TEM). The size distribution in whisker-like and nanocrystalline materials are in the range of 10～50μm and 10～20nm respectively. The whisker MOS is metastable phase in MgSO4-NaOH-H2O system at 140℃，whereas nanometer MOS is stable phase.
|
| 关 键 词： | 水热合成 硫氧镁 形貌 |
Hydrothermal Synthesis and the Effect of Reaction Time on Morphology of MgSO4 · 5Mg(OH)2 · 3H2O |
| |
| ZHU Li-Xi,YUE Tao,GAO Shi-Yang and XIA Shu-Ping. Hydrothermal Synthesis and the Effect of Reaction Time on Morphology of MgSO4 · 5Mg(OH)2 · 3H2O[J]. Chinese Journal of Inorganic Chemistry, 2003, 19(1): 99-102 |
| |
| Authors: | ZHU Li-Xi YUE Tao GAO Shi-Yang XIA Shu-Ping |
| |
| Abstract: | Both whisker and nanometer MgSO4 @ 5Mg(OH)2 @ 3H2O(MOS) were prepared by hydrothermal method at140℃ for different times, using NaOH and MgSO4 @ 7H2O as raw materials. The MgSO4 @ 5Mg(OH)2 @ 3H2O part-icles were characterized by powder X-ray diffraction(XRD), thermal analysis(TGA-DSC), infrared spectroscopy(FT-IR), transmission electron microscopy (SEM) and scanning electron microscopy (TEM). The size distribution inwhisker-like and nanocrystalline materials are in the range of 10～50μm and 10～20nm respectively. The whiskerMOS is metastable phase in MgSO4-NaOH-H2O system at 140℃, whereas nanometer MOS is stable phase. |
| |
| Keywords: | hydrothermal synthesis magnesium oxysulfate morphology |
|
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
|
点击此处可从《无机化学学报》下载全文 |
