Advantages of using a mercury coated, micro-wire, electrode in adsorptive cathodic stripping voltammetry

A mercury coated, gold, micro-wire electrode is used here for the determination of iron in seawater by catalytic cathodic stripping voltammetry (CSV) with a limit of detection of 0.1 nM Fe at a 60 s adsorption time. It was found that the electrode surface is stable for extended periods of analyses (at least five days) and that it is reactivated by briefly (2 s) applying a negative potential prior to each scan. Advantages of this electrode over mercury drop electrodes are that metallic mercury use is eliminated and that it can be readily used for flow analysis. This is demonstrated here by the determination of iron in seawater by continuous flow analysis. It is likely that this method can be extended to other elements. Experiments using bismuth coated, carbon fibre, electrodes showed that the bismuth catalyses the oxidation of the important oxidants bromate and hydrogen peroxide, which makes it impossible to use bismuth based electrodes for catalytic CSV involving these oxidants. For this reason mercury coated electrodes retain a major advantage for catalytic voltammetric analyses.