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Development of a fluorescence lifetime-based sol-gel humidity sensor
Authors:Orla McGaughey  José Vicente Ros-Lis  Aisling K McEvoy  Brian D MacCraith
Institution:a Optical Sensors Laboratory, National Centre for Sensor Research, School of Physical Sciences, Dublin City University, Dublin 9, Ireland
b Universidad Politécnica de Valencia, Camino de Vera s/n, E-46022 Valencia, Spain
c Gas Sensor Solutions Ltd., The Invent Centre, Glasnevin, Dublin 9, Ireland
Abstract:A sol-gel-based optical sensor for the measurement of relative humidity has been developed. It is based on the changes in fluorescence intensity and/or lifetime of the ruthenium complex, ruthenium(II)diphenylphenanthroline-dipyridophenazinehexafluorophosphate. Sensitivity to relative humidity has been demonstrated over the range 0-100% relative humidity. This sensor has been developed for application in the field of indoor air-quality monitoring and displays a limit of detection of 0.35% relative humidity and a resolution of 1.13% over the concentration range of interest (0-50% relative humidity). The effects of varying process parameters on the sensor performance were studied along with the effects of cross-sensitivity to molecular oxygen.
Keywords:Fluorescence lifetime  Relative humidity  Sol-gel  Sensor
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