A Novel Three-dimensional Ni Coordination Polymer Based on Flexible Di-carboxylate Ligand and 4,4-Pyridine: Synthesis, Characterization and Topological Analysis |
| |
引用本文: | 陈友存,庄杰,王素娜,王彦.A Novel Three-dimensional Ni Coordination Polymer Based on Flexible Di-carboxylate Ligand and 4,4-Pyridine: Synthesis, Characterization and Topological Analysis[J].结构化学,2012,31(9):1339-1345. |
| |
作者姓名: | 陈友存 庄杰 王素娜 王彦 |
| |
作者单位: | Anhui Provincial Laboratory of Optoelectronic and Magnetism Functional Materials, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, China;State Key Laboratory of Coordination Chemistry, Nanjing University;School of Chemistry and Chemical Engineering, Liaocheng University |
| |
基金项目: | Supported by the National Natural Science Foundation of China (No. 20771006, 20901004 and 20801025) |
| |
摘 要: | A novel Ni(II) coordination polymer Ni(dtba)(4,4′-bpy)] (1, H2dtba = 2,2′-dithio- bisbenzoic acid, 4,4′-bpy = 4,4′-bipyridine) has been synthesized by H2dtba and Ni(CH3COO)2·4H2O with exo-bidentate rigid ligand 4,4′-bpy by using hydrothermal method, and its structure was determined by single-crystal X-ray diffraction. X-ray crystal structure analysis reveals that complex 1 crystallizes in monoclinic, space group Cc with a = 11.7624(9), b = 18.7933(19), c = 10.3071(11), β = 97.6510(10)°, V = 2258.2(4)3, Z = 4, C24H16N2NiO4S2, Mr = 519.22, Dc = 1.527 g/cm3, μ = 1.079 mm-1 and F(000) = 1064. The structure was solved by direct methods and refined to R = 0.0434 and wR = 0.1000 for 3281 observed reflections (I > 2σ(I)). The coordination environment of Ni(II) is a distorted octahedron, and a three-dimensional structure was formed with the coordination effect of dtba2- and 4,4′-bpy ligands. The topological analysis reveals that the whole framework of 1 is a 2-nodal net of (52.6)(53.64.72.8) topology. The thermal stability and XRD pattern of 1 were also investigated.
|
关 键 词: | self-assembly exo-bidentate ligands three-dimensional framework topo-chemistry |
本文献已被 CNKI 维普 万方数据 等数据库收录! |
|