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Functional composites based on polybenzimidazole and graphite nanoplates
Authors:B. Ch. Kholkhoev  E. N. Gorenskaya  S. A. Bal’zhinov  I. A. Farion  G. N. Batorova  A. V. Nomoev  P. S. Timashev  B. R. Radnaev  R. K. Chailakhyan  V. E. Fedorov  V. F. Burdukovskii
Abstract:A procedure was developed for preparing stable dispersions of graphite nanoplates with the concentration of up to 25 mg mL–1 by two-step ultrasonic treatment of graphite in N-methyl-2-pyrrolidone. A series of elastic films based on poly-2,2′-p-oxydiphenylene-5,5′-bisdibenzimidazole oxide with the filler content of up to 45 wt % were prepared from such dispersions. Introduction of the nanoadditive into the matrix of the heterocyclic polymer results in 47% enhancement of the tensile strength of the materials and in an increase in the temperature of the 10% weight loss by 52–81°C. In addition, the films are characterized by high electrical conductivity reaching 480 S cm–1 for the composite with 45 wt % graphite nanoplates and exhibit tensoresistive properties, which allows using them in various electrotechnical devices and fabric engineering structures.
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