Faujasite-type zeolites modified with iron perfluorophthalocyanines: Synthesis and characterization |
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| Institution: | 1. School of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, China;2. Guangdong Provincial Key Laboratory of Mineral Physics and Material Research & Development, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China |
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| Abstract: | The synthesis and characterization of hexadeca- or perfluorophthalocyanine complexes of iron(II) (FeF16Pc) in synthetic faujasite-type zeolites is reported. The encapsulation of FeF16Pc in NaY zeolite by the template synthesis method as well as the synthesis of NaX around FeF16Pc are discussed. A spectroscopic (UV—VIS, IR) and electrochemical analysis of the modified zeolites, providing evidence for encapsulation, is presented and compared with the unsubstituted FePc complex. |
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