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Far infrared spectra of mono- and bisphthalocyanine derivatives
Affiliation:1. Department of Hepato-Pancreato-Biliary and Liver Transplant Surgery, Queen Elizabeth University Hospitals Birmingham NHS Foundation Trust, B15 2TH, UK;2. Division of Hepatobiliary Surgery, San Raffaele Hospital, Via Olgettina 60, 20132, Milan, Italy;1. Department of Pain, The First Affiliated Hospital of Anhui Medical University, Hefei 230022, China;2. Inflammation and Immune Mediated Diseases Laboratory of Anhui Province, Hefei 230022, China;3. Department of Gynecology, Maternity and Child Health Hospital Affiliated to Anhui Medical University, Anhui Province Maternity and Child Health Hospital, No. 15 Yimin Street, Hefei 230001, Anhui, China;4. Department of Radiology, The First Affiliated Hospital of Anhui Medical University, No. 218 Jixi Road, Hefei 230032, Anhui, China;1. Clinic of Surgery and Anaesthesiology of Domestic Animals, Faculty of Veterinary Medicine, Ghent University, Merelbeke, Belgium;2. Department of Animal Medicine and Surgery, Faculty of Veterinary Medicine, University of Murcia, Murcia, Spain;1. College of Pharmacy, Qiqihar Medical University, 161006 Qiqihar, China;2. Key Laboratory of Forest Plant Ecology, Northeast Forestry University, 150040 Harbin, China
Abstract:The far infrared spectra of a series of unsubstituted monophthalocyanine (Pc) and di-Pc derivatives and some of the corresponding tetra-tert-butyl substituted Pc molecules are reported. The infrared data were recorded between 100 and 4.50 cm−1. The vibrational assignment of metal-nitrogen stretching frequencies is discussed. The far infrared data for tert-butyl Pc derivatives and a group of C Pc complexes are presented here for the first time.
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