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Medium control in a competitive hydrogen bonding system
Institution:1. School of Science, Xihua University, 999 Jinzhou Road, Chengdu, Sichuan 610039, China;2. National Engineering Research Center for Biomaterials, Sichuan University, 29 Wangjiang Road, Chengdu, Sichuan 610064, China;1. East Tennessee State University Bill Gatton College of Pharmacy, Johnson City, Tennessee;2. East Tennessee State University Quillen College of Medicine, Johnson City, Tennessee
Abstract:Infrared spectroscopic analysis of solutions containing 4-hydroxyacetophenone (HAP) and the model surfactant 2-(2-hexyloxyethoxy)ethanol (HOEE) reveal a medium dependent hydrogen bonding competition between homomolecular association (HAP]n + HOEE]n) and heteromolecular association (HAP-HOEE]n) with the former being favoured by low polarity solvents.
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